Right click on the file, select "Properties" and write down the file size in bytes (call this "A").
Right click on the drive letter for the USB stick, select properties, and write down the capacity in Bytes (call this "B").
I would expect A to be less than B - unless you are using compression. Comparing megabytes and gigabytes is usually futile as different folks use different methods of defining what they mean.
SI units mean that a mega-X is one million of X, and a giga-X is one billion of it. In computers, however, a "megabyte" is 1024x1024 = 1,048,576 Bytes. A gigabyte multiplies by another 1024 - however some computing applications quantify things in SI units, rather than computing units. I seem to recall some hard drive vendor got their wrists slapped for this as it artificially inflated the stated size of their drives.